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Title

Stereochemical study of the allylation of 1-phenylsulfinylethyl and 1-phenylsulfinyl-2,2,2-trifluoroethyl radicals

Authors
Renaud, P.
Gerster, M.
Schenk, K.
Published in Tetrahedron Letters. 1994, vol. 35, no. 11, p. 1703-1706
Abstract The stereochemistry of the reactions of 1-phenylsulfinylethyl radical (1r) and 1-phenylsulfinyl-2,2,2-trifluoroethyl radical (2r) with allylstannanes has been examined. Preferential formation of products of opposite relative configuration has been observed. Conformational analysis of the radical intermediates (AM1 calculations) allows to rationalize the results
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RENAUD, P. et al. Stereochemical study of the allylation of 1-phenylsulfinylethyl and 1-phenylsulfinyl-2,2,2-trifluoroethyl radicals. In: Tetrahedron Letters, 1994, vol. 35, n° 11, p. 1703-1706. https://archive-ouverte.unige.ch/unige:9970

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Deposited on : 2010-08-06

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