A model for the stereoselectivity of radical mediated reductive alkylation of acyclic enamines

Renaud, P.; Bjorup, P.; Carrupt, Pierre-Alain; Schenk, K.; Schubert, S.

doi:10.1055/s-1992-21316

Scientific article

English

A model for the stereoselectivity of radical mediated reductive alkylation of acyclic enamines

ContributorsRenaud, P.; Bjorup, P.; Carrupt, Pierre-Alain; Schenk, K.; Schubert, S.

Published inSynlett, no. 3, p. 211-213

Publication date1992

Abstract

The radical mediated reductive alkylation of enamines [e.g., (E)-1-phenyl-1-pyrrolidino-1-propene (1)] derived from propiophenone is investigated. The observed stereoselectivities are explained with a model based on semiempirical calculations of the radical intermediate conformation

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Citation (ISO format)

RENAUD, P. et al. A model for the stereoselectivity of radical mediated reductive alkylation of acyclic enamines. In: Synlett, 1992, n° 3, p. 211–213. doi: 10.1055/s-1992-21316

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PID : unige:9968
DOI : 10.1055/s-1992-21316

Journal ISSN0936-5214

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A model for the stereoselectivity of radical mediated reductive alkylation of acyclic enamines

The radical mediated reductive alkylation of enamines [e.g., (E)-1-phenyl-1-pyrrolidino-1-propene (1)] derived from propiophenone is investigated. The observed stereoselectivities are explained with a model based on semiempirical calculations of the radical intermediate conformation

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