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Title

Conformational-analysis of alpha-methoxyketones : a photoelectron spectroscopic investigation of 3-Methoxybicyclo[2.2.1]Heptan-2-Ones

Authors
Cossy, J.
Pete, J. P.
Gleiter, R.
Flatow, A.
Vogel, Pierre
Published in Tetrahedron. 1992, vol. 48, no. 12, p. 2401-2414
Abstract The photoelectron spectra of 3-endo-(2), of 3-exo-methoxybicyclo[2.2.1]heptan-2-one (3) and of 2-endo,3-endo-dimethoxybicyclo[2.2.1]heptane (4) are analyzed in comparison with data reported for other analogous systems and with predictions based on quantum mechanical calculations. In 2, the ''homo-gauche'' conformer (2G) is more stable than the ''homo-anti'' conformer (2A) whereas in 3, the ''homo-anti'' conformer (3A) is slightly more stable than the corresponding ''homo-gauche'' rotamer (3G)
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COSSY, J. et al. Conformational-analysis of alpha-methoxyketones : a photoelectron spectroscopic investigation of 3-Methoxybicyclo[2.2.1]Heptan-2-Ones. In: Tetrahedron, 1992, vol. 48, n° 12, p. 2401-2414. https://archive-ouverte.unige.ch/unige:9919

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Deposited on : 2010-08-06

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