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Di-μ-bromo-bis{[(2,4,6-tris-tert-butylphenyl)phosphanediylmethyl-P]phenyl-C2}dipalladium

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Published in Acta Crystallographica. C, Crystal Structure Communications. 1997, vol. 53, no. 7, p. 866-868
Abstract The crystal structure of the title compound, [Pd<sub>2</sub>Br<sub>2</sub>(C<sub>25</sub>H<sub>34</sub>P)<sub>2</sub>], a new binuclear phospha-alkene compound containing a trivalent P atom shows a centrosymmetric dimeric arrangement. The Pd<sub>2</sub>Br<sub>2</sub> core is planar and adopts an irregular diamond shape. The coordination of the Pd atom is square planar. No stacking interactions were observed in the molecular packing.
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CHENTIT, Mostafa, GEOFFROY, Michel, BERNARDINELLI, Gérald Hugues. Di-μ-bromo-bis{[(2,4,6-tris-tert-butylphenyl)phosphanediylmethyl-P]phenyl-C2}dipalladium. In: Acta Crystallographica. C, Crystal Structure Communications, 1997, vol. 53, n° 7, p. 866-868. https://archive-ouverte.unige.ch/unige:81161

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