Di-μ-bromo-bis{[(2,4,6-tris-tert-butylphenyl)phosphanediylmethyl-P]phenyl-C<sup>2</sup>}dipalladium

Chentit, Mostafa; Geoffroy, Michel; Bernardinelli, Gérald Hugues

Scientific article

English

Di-μ-bromo-bis{[(2,4,6-tris-tert-butylphenyl)phosphanediylmethyl-P]phenyl-C²}dipalladium

ContributorsChentit, Mostafa; Geoffroy, Michel; Bernardinelli, Gérald Hugues

Published inActa crystallographica. Section C, Crystal structure communications, vol. 53, no. 7, p. 866-868

Publication date1997

Abstract

The crystal structure of the title compound, [Pd₂Br₂(C₂₅H₃₄P)₂], a new binuclear phospha-alkene compound containing a trivalent P atom shows a centrosymmetric dimeric arrangement. The Pd₂Br₂ core is planar and adopts an irregular diamond shape. The coordination of the Pd atom is square planar. No stacking interactions were observed in the molecular packing.

Affiliation entities

Citation (ISO format)

CHENTIT, Mostafa, GEOFFROY, Michel, BERNARDINELLI, Gérald Hugues. Di-μ-bromo-bis{[(2,4,6-tris-tert-butylphenyl)phosphanediylmethyl-P]phenyl-C²}dipalladium. In: Acta crystallographica. Section C, Crystal structure communications, 1997, vol. 53, n° 7, p. 866–868.

Article (Published version)

Identifiers

PID : unige:81161

Journal ISSN0108-2701

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Creation01/21/2016 10:47:00 AM

First validation01/21/2016 10:47:00 AM

Update time03/15/2023 12:10:40 AM

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Di-μ-bromo-bis{[(2,4,6-tris-tert-butylphenyl)phosphanediylmethyl-P]phenyl-C2}dipalladium

Technical informations

Di-μ-bromo-bis{[(2,4,6-tris-tert-butylphenyl)phosphanediylmethyl-P]phenyl-C²}dipalladium