Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

Mercier, Audrey Catherine Marie; Yeo, Wee Chuan; Chou, Jingyu; Chaudhuri, Piyali; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

doi:10.1039/b910977c

Scientific article

English

Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

ContributorsMercier, Audrey Catherine Marie; Yeo, Wee Chuan; Chou, Jingyu; Chaudhuri, Piyali; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

Published inChemical communications, no. 35, p. 5227-5229

Publication date2009

Abstract

Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF6], the precursor of [RuCp(CH3CN)3][PF6], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MERCIER, Audrey Catherine Marie et al. Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis. In: Chemical communications, 2009, n° 35, p. 5227–5229. doi: 10.1039/b910977c

Article

Identifiers

PID : unige:7030
DOI : 10.1039/b910977c
PMID : 19707628

ISSN of the journal1359-7345

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Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

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