Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

Mercier, Audrey Catherine Marie; Yeo, Wee Chuan; Chou, Jingyu; Chaudhuri, Piyali; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

doi:10.1039/b910977c

Scientific article

English

Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

Contributors

Mercier, Audrey Catherine Marie; Yeo, Wee Chuan; Chou, Jingyu; Chaudhuri, Piyali; Bernardinelli, Gérald Hugues; Kundig, Ernst Peter

Published in

Chemical communications, no. 35, p. 5227-5229

Publication date

2009

Abstract

Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF6], the precursor of [RuCp(CH3CN)3][PF6], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MERCIER, Audrey Catherine Marie et al. Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis. In: Chemical communications, 2009, n° 35, p. 5227–5229. doi: 10.1039/b910977c

Article

Identifiers

PID : unige:7030
DOI : 10.1039/b910977c
PMID : 19707628

Journal ISSN

1359-7345

665views

9downloads

Creation

18/06/2010 08:55:17

First validation

18/06/2010 08:55:17

Update

14/03/2023 15:42:19

Status update

14/03/2023 15:42:19

Last indexation

10/06/2025 21:34:45

Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

Contributors

Published in

Publication date

Abstract

UNIGE affiliation entities

Citation (ISO format)

Main files (1)

Identifiers

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation