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Scientific article
English

Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki–Miyaura Coupling Reactions

Published inOrganometallics, vol. 33, no. 1, p. 260-266
Publication date2014
Abstract

PEPPSI complexes incorporating chiral N-heterocyclic carbene (NHC) ligands based on 2,2-dimethyl-1-(o-substituted aryl)propan-1-amines were synthesized. Two complexes, with one saturated and one unsaturated NHC ligand, were structurally characterized. The chiral PEPPSI complexes were used in asymmetric Suzuki–Miyaura reactions, giving atropisomeric biaryl products in modest to good enantiomeric ratios.

Citation (ISO format)
BENHAMOU, Laure, BESNARD, Céline, KUNDIG, Ernst Peter. Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki–Miyaura Coupling Reactions. In: Organometallics, 2014, vol. 33, n° 1, p. 260–266. doi: 10.1021/om4009982
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ISSN of the journal0276-7333
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Creation01/13/2014 9:46:00 AM
First validation01/13/2014 9:46:00 AM
Update time03/14/2023 8:50:39 PM
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