Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki

Article Article scientifique Article Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki–Miyaura Coupling Reactions eng 2014 author Benhamou Laure 742997 author Besnard Céline 682138 author Kundig Ernst Peter 26401 260-266 10.1021/om4009982 0276-7333 PEPPSI complexes incorporating chiral N-heterocyclic carbene (NHC) ligands based on 2,2-dimethyl-1-(o-substituted aryl)propan-1-amines were synthesized. Two complexes, with one saturated and one unsaturated NHC ligand, were structurally characterized. The chiral PEPPSI complexes were used in asymmetric Suzuki–Miyaura reactions, giving atropisomeric biaryl products in modest to good enantiomeric ratios. Dewey 540 36 Département de chimie organique 141 false Organometallics 33 1 45c576df-f315-4b63-af4f-71c63556305f Article (Published version) Restricted om4009982.pdf 1191710 application/pdf restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki–Miyaura Coupling Reactions	Organometallics			2014	696	0

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Benhamou, Laure