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Scientific article
English

Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins

Published inChemistry, vol. 19, no. 34, p. 11352-11363
Publication date2013
Abstract

The copper-catalysed conjugate addition of trialkylaluminium and dialkylzinc reagents to polyconjugated nitroolefins (nitrodiene and nitroenyne derivatives) is reported. A reversed Josiphos ligand L7 allows for the selective 1,4- or 1,6-addition with high enantioselectivities.

Keywords
  • Asymmetric catalysis
  • Conjugate addition
  • Copper
  • Ligand effects
  • Phosphine ligands
Citation (ISO format)
TISSOT, Matthieu, ALEXAKIS, Alexandre. Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins. In: Chemistry, 2013, vol. 19, n° 34, p. 11352–11363. doi: 10.1002/chem.201300538
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Article (Published version)
accessLevelRestricted
Identifiers
ISSN of the journal0947-6539
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Creation09/02/2013 4:53:00 PM
First validation09/02/2013 4:53:00 PM
Update time03/14/2023 8:23:53 PM
Status update03/14/2023 8:23:53 PM
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