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Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins

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Published in Chemistry - A European Journal. 2013, vol. 19, no. 34, p. 11352-11363
Abstract The copper-catalysed conjugate addition of trialkylaluminium and dialkylzinc reagents to polyconjugated nitroolefins (nitrodiene and nitroenyne derivatives) is reported. A reversed Josiphos ligand L7 allows for the selective 1,4- or 1,6-addition with high enantioselectivities.
Keywords Asymmetric catalysisConjugate additionCopperLigand effectsPhosphine ligands
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Other version: http://doi.wiley.com/10.1002/chem.201300538
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TISSOT, Matthieu, ALEXAKIS, Alexandre. Enantio- and Regioselective Conjugate Addition of Organometallic Reagents to Linear Polyconjugated Nitroolefins. In: Chemistry - A European Journal, 2013, vol. 19, n° 34, p. 11352-11363. https://archive-ouverte.unige.ch/unige:29564

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Deposited on : 2013-09-04

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