Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium

Chentit, Mostafa; Geoffroy, Michel; Bernardinelli, Gérald Hugues

doi:10.1107/S0108270197003235

Scientific article

English

Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium

ContributorsChentit, Mostafa; Geoffroy, Michel; Bernardinelli, Gérald Hugues

Published inActa crystallographica. Section C, Crystal structure communications, vol. 53, no. 11, p. 866-868

Publication date1997

Abstract

The crystal structure of the title compound, [Pd2Br2(C25H34P)2], a new binuclear phospha-alkene compound containing a trivalent P atom shows a centrosymmetric dimeric arrangement. The Pd2Br2 core is planar and adopts an irregular diamond shape. The coordination of the Pd atom is square planar. No stacking interactions were observed in the molecular packing.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Research groups

Groupe Geoffroy

Citation (ISO format)

CHENTIT, Mostafa, GEOFFROY, Michel, BERNARDINELLI, Gérald Hugues. Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium. In: Acta crystallographica. Section C, Crystal structure communications, 1997, vol. 53, n° 11, p. 866–868. doi: 10.1107/S0108270197003235

Identifiers

PID : unige:2782
DOI : 10.1107/S0108270197003235

Commercial URLhttp://journals.iucr.org/c/issues/1997/07/00/pa1251/pa1251.pdf

Journal ISSN0108-2701

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Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium

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