Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium

Chentit, Mostafa; Geoffroy, Michel; Bernardinelli, Gérald Hugues

doi:10.1107/S0108270197003235

Article scientifique

Anglais

Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium

Contributeurs/tricesChentit, Mostafa; Geoffroy, Michel; Bernardinelli, Gérald Hugues

Publié dansActa crystallographica. Section C, Crystal structure communications, vol. 53, no. 11, p. 866-868

Date de publication1997

Résumé

The crystal structure of the title compound, [Pd2Br2(C25H34P)2], a new binuclear phospha-alkene compound containing a trivalent P atom shows a centrosymmetric dimeric arrangement. The Pd2Br2 core is planar and adopts an irregular diamond shape. The coordination of the Pd atom is square planar. No stacking interactions were observed in the molecular packing.

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Groupe de recherche

Groupe Geoffroy

Citation (format ISO)

CHENTIT, Mostafa, GEOFFROY, Michel, BERNARDINELLI, Gérald Hugues. Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium. In: Acta crystallographica. Section C, Crystal structure communications, 1997, vol. 53, n° 11, p. 866–868. doi: 10.1107/S0108270197003235

Identifiants

PID : unige:2782
DOI : 10.1107/S0108270197003235

URL commercialhttp://journals.iucr.org/c/issues/1997/07/00/pa1251/pa1251.pdf

ISSN du journal0108-2701

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Di-[mu]-bromo-bis{[(2,4,6-tris-tert-butyl-phenyl)phosphanediylmethyl-P]phenyl-C2}-dipalladium

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