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New regio and stereoselective intermolecular Pauson–Khand reactions of allenamides

Published inTetrahedron letters, vol. 45, no. 23, p. 4441-4444
Publication date2004
Abstract

Intermolecular Pauson–Khand reactions are still quite limited in scope and yields. There are also few reports using allenes as the olefinic part in this version. We report herein new regio and stereoselective reactions of allenamides with several alkynes. These reactions give functionalized cyclopentenones bearing an exocyclic enamide, which can be useful synthetic intermediates.

Keywords
  • Intermolecular Pauson–Khand
  • Allenamides
  • Cobalt
Affiliation entities Not a UNIGE publication
Citation (ISO format)
AÑORBE, Loreto et al. New regio and stereoselective intermolecular Pauson–Khand reactions of allenamides. In: Tetrahedron letters, 2004, vol. 45, n° 23, p. 4441–4444. doi: 10.1016/j.tetlet.2004.04.061
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Identifiers
Journal ISSN0040-4039
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