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Modular Asymmetric Synthesis of Pochonin C

Barluenga, Sofia
Lopez, Pilar
Moulin, Emilie
Published in Angewandte Chemie: International Edition. 2004, vol. 43, no. 26, p. 3467-3470
Abstract Back to its origins: Pochonin C was synthesized in 11 steps from the four fragments shown in the scheme. This asymmetric synthesis and the conversion of pochonin C into radicicol defines the configuration at the center bearing the chlorine atom as S. Ipc=isopenocampheyl, PG=protecting group.
Keywords asymmetric synthesisconformation analysismetathesisnatural productstotal synthesis
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BARLUENGA, Sofia et al. Modular Asymmetric Synthesis of Pochonin C. In: Angewandte Chemie: International Edition, 2004, vol. 43, n° 26, p. 3467-3470. doi: 10.1002/anie.200454108

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Deposited on : 2012-12-19

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