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Solid-Phase Synthesis of Oligosaccharides: Construction of a Dodecasaccharide

Nicolaou, K. C.
Watanabe, Nobuhide
Li, Jim
Pastor, Joaquín
Published in Angewandte Chemie: International Edition. 1998, vol. 37, no. 11, p. 1559-1561
Abstract Complicated oligosaccharides such as dodecasaccharide 1 can be constructed by a new solid-phase strategy. The attachment to the polymeric support (gray sphere) is through a photolabile linker (structure I), and thioglycosides serve as carbohydrate donors. Bn=benzyl, Bz=benzoyl.
Keywords Block-type constructionOligosaccharidesPhotolabile linkerSolid-phase synthesisThioglycoside
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NICOLAOU, K. C. et al. Solid-Phase Synthesis of Oligosaccharides: Construction of a Dodecasaccharide. In: Angewandte Chemie: International Edition, 1998, vol. 37, n° 11, p. 1559-1561.

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