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An expedient approach to the total synthesis of (+)-5-epi-eudesm-4(15)-ene-1β,6β-diol

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Published in Chemical Communications. 2012, vol. 48, no. 91, p. 11241-11243
Abstract The first total synthesis of (+)-5-epi-eudesm-4(15)-ene-1β,6β-diol has been achieved in 12 steps starting from the known (−)-cis-piperitol and by using a chelation controlled glycolate enolate Ireland–Claisen rearrangement and an intramolecular nitrile oxide dipolar cycloaddition as key steps.
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Other version: http://xlink.rsc.org/?DOI=c2cc36260k
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PARTHASARATHY, Gowrisankar, BESNARD, Céline, KUNDIG, Ernst Peter. An expedient approach to the total synthesis of (+)-5-epi-eudesm-4(15)-ene-1β,6β-diol. In: Chemical Communications, 2012, vol. 48, n° 91, p. 11241-11243. https://archive-ouverte.unige.ch/unige:23573

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Deposited on : 2012-10-29

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