An expedient approach to the total synthesis of (+)-5-epi-eudesm-4(15)-ene-1β,6β-diol

Article Article scientifique Article An expedient approach to the total synthesis of (+)-5-epi-eudesm-4(15)-ene-1β,6β-diol eng 2012 author Parthasarathy Gowrisankar 760444 author Besnard Céline 682138 author Kundig Ernst Peter 26401 11241-11243 10.1039/c2cc36260k 1359-7345 http://xlink.rsc.org/?DOI=c2cc36260k The first total synthesis of (+)-5-epi-eudesm-4(15)-ene-1β,6β-diol has been achieved in 12 steps starting from the known (−)-cis-piperitol and by using a chelation controlled glycolate enolate Ireland–Claisen rearrangement and an intramolecular nitrile oxide dipolar cycloaddition as key steps. Dewey 540 36 Département de chimie organique 141 false Chemical communications 48 91 6bed5633-dff4-4051-b2f9-6519f1e21395 Article (Published version) Restricted c2cc36260k.pdf 1150845 application/pdf restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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An expedient approach to the total synthesis of (+)-5-epi-eudesm-4(15)-ene-1β,6β-diol	Chemical communications			2012	731	0

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Parthasarathy, Gowrisankar