Influence of the water content of the solvent on the product distribution in the electrohydrodimerization of 2-cyclohexenones

Tissot, Paul; Surbeck, Jean-Paul; Gulacar, Fazil; Margaretha, Paul

doi:10.1002/hlca.19810640536

Scientific article

English

Influence of the water content of the solvent on the product distribution in the electrohydrodimerization of 2-cyclohexenones

ContributorsTissot, Paul; Surbeck, Jean-Paul; Gulacar, Fazil; Margaretha, Paul

Published inHelvetica chimica acta, vol. 64, no. 5, p. 1570-1574; 148

Publication date1981

Abstract

The product distribution of compounds 2, 3 and 4 formed in the electrohydrodimerization (EHD) of 1 was determined as function of the water content of the solvent (CH₃CN). The presence of water favours the formation of the glycols 4 and reduces the relative amounts of 1,6-diketones 2 and hydroxyketones 3, as determined by GC./MS.-analysis.

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Citation (ISO format)

TISSOT, Paul et al. Influence of the water content of the solvent on the product distribution in the electrohydrodimerization of 2-cyclohexenones. In: Helvetica chimica acta, 1981, vol. 64, n° 5, p. 1570–1574. doi: 10.1002/hlca.19810640536

Article (Published version)

Identifiers

PID : unige:180708
DOI : 10.1002/hlca.19810640536

Journal ISSN0018-019X

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Influence of the water content of the solvent on the product distribution in the electrohydrodimerization of 2-cyclohexenones

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