en
Scientific article
Letter
English

Asymmetric 1,4-additions of coordinated MeCu.BF3 to chiral enoates: enantioselective syntheses of (S)-(−)-citronellic acid

Published inTetrahedron letters, vol. 24, no. 45, p. 4971-4974
Publication date1983
Abstract

nBu3P- or cyanide-stabilized RCu.BF3 (R-Me, 4-Me-3-pentenyl) undergo efficient 1,4-additions to neopentylether-shielded trans-enoates. Thus chiral β-substituted carboxylic acids e.g. (S)-citronellic acid were obtained in high e.e. (Schemes 2 and 4).

eng
Citation (ISO format)
VON OPPOLZER, Wolfgang et al. Asymmetric 1,4-additions of coordinated MeCu.BF<sub>3</sub> to chiral enoates: enantioselective syntheses of (S)-(−)-citronellic acid. In: Tetrahedron letters, 1983, vol. 24, n° 45, p. 4971–4974. doi: 10.1016/S0040-4039(01)99824-7
Main files (1)
Article (Published version)
accessLevelRestricted
Identifiers
ISSN of the journal0040-4039
19views
0downloads

Technical informations

Creation04/14/2023 9:49:03 AM
First validation04/14/2023 10:13:29 AM
Update time04/14/2023 10:13:29 AM
Status update04/14/2023 10:13:29 AM
Last indexation01/17/2024 11:36:42 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack