Asymmetric 1,4-additions of coordinated MeCu.BF3 to chiral enoates: enantioselective syntheses of (S)-(−)-citronellic acid

Article Article scientifique Lettre Asymmetric 1,4-additions of coordinated MeCu.BF3 to chiral enoates: enantioselective syntheses of (S)-(−)-citronellic acid eng 1983 author Von Oppolzer Wolfgang 25270 author Moretti Robert 68810 author Godel Thierry 658665 author Meunier Anne Marie Yvonne 26594 author Loeher Heinz Joséf 73586 4971-4974 10.1016/S0040-4039(01)99824-7 0040-4039 https://linkinghub.elsevier.com/retrieve/pii/S0040403901998247 nBu3P- or cyanide-stabilized RCu.BF3 (R-Me, 4-Me-3-pentenyl) undergo efficient 1,4-additions to neopentylether-shielded trans-enoates. Thus chiral β-substituted carboxylic acids e.g. (S)-citronellic acid were obtained in high e.e. (Schemes 2 and 4). Dewey 540 36 Département de chimie organique 141 false Tetrahedron letters 24 45 3ddf1d91-7c50-4fa1-99a6-c655ad549e4c Article (Published version) Restricted Oppolzer_TL_1983244971.pdf 1909025 application/pdf cd6f407cc1f34878fcd788a981a9e7f75e026504a86f7b11a3626407ef244801 restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

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Asymmetric 1,4-additions of coordinated MeCu.BF₃ to chiral enoates: enantioselective syntheses of (S)-(−)-citronellic acid	Tetrahedron letters			1983	51	0

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Meunier, Anne Marie Yvonne