The coherent interaction of solid-state spins with both optical and microwave fields provides a platform for a range of quantum technologies, such as quantum sensing, microwave-to-optical quantum transduction and optical quantum memories. Rare-earth ions with electronic spins are interesting in this context. In this work, we use a loop-gap microwave resonator to coherently drive optical and microwave clock transitions simultaneously in a ¹⁷¹ Yb ³⁺ :Y ₂ SiO ₅ crystal, achieving a Rabi frequency of 0.56 MHz at 2.497 GHz over a 1-cm long crystal. Furthermore, we provide insights into the spin dephasing at very low fields, showing that superhyperfine-induced collapse of the Hahn echo plays an important role. Our calculations and measurements reveal that the effective magnetic moment can be manipulated in ¹⁷¹ Yb ³⁺ :Y ₂ SiO ₅ , which suppresses the superhyperfine interaction at the clock transition. At a doping concentration of 2 ppm and 3.4 K, we achieve spin coherence time of 10.0 ± 0.4 ms.