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Scientific article
English

New Experimental Conditions for Tandem hydroalumination/Cu-Catalyzed Asymmetric Conjugate Additions to β-Substituted Cyclic Enones

Published inOrganic letters, vol. 13, no. 12, p. 3040-3043
Publication date2011
Abstract

Readily available alkenylalanes, arising from hydroalumination of unprotected terminal alkynes, have been directly employed for the copper-catalyzed asymmetric conjugate addition (ACA) to β-substituted cyclic enones. The desired products, containing a quaternary stereogenic center, are generally obtained in good yields and enantioselectivities.

Citation (ISO format)
MUELLER, Daniel, TISSOT, Matthieu, ALEXAKIS, Alexandre. New Experimental Conditions for Tandem hydroalumination/Cu-Catalyzed Asymmetric Conjugate Additions to β-Substituted Cyclic Enones. In: Organic letters, 2011, vol. 13, n° 12, p. 3040–3043. doi: 10.1021/ol200898c
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ISSN of the journal1523-7052
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Creation06/20/2011 9:55:00 AM
First validation06/20/2011 9:55:00 AM
Update time03/14/2023 4:52:21 PM
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