en
Scientific article
Open access
English

Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers

Published inACS Organic & Inorganic Au, vol. 1, no. 1, p. 11-17
Publication date2021-10-06
First online date2021-05-05
Abstract

Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH3CN)3][BArF] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide intermediates.

eng
Keywords
  • Carbonyl ylide reactivity
  • CpRu catalysis
  • Diazo decomposition
  • Enol ethers
  • Malonate
Citation (ISO format)
VINAS, Julia et al. Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers. In: ACS Organic & Inorganic Au, 2021, vol. 1, n° 1, p. 11–17. doi: 10.1021/acsorginorgau.1c00006
Main files (1)
Article (Published version)
Identifiers
ISSN of the journal2694-247X
164views
81downloads

Technical informations

Creation10/06/2021 11:03:00 AM
First validation10/06/2021 11:03:00 AM
Update time03/16/2023 1:26:38 AM
Status update03/16/2023 1:26:38 AM
Last indexation05/06/2024 8:15:56 AM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack