Domino Asymmetric Conjugate Addition

Article Article scientifique Article Domino Asymmetric Conjugate Addition–Conjugate Addition eng 2014 author Germain Nicolas 733490 author Schlaefli Dorian 733471 author Chellat Mathieu 765550 author Rosset Stéphane 28170 author Alexakis Alexandre 123950 2006-2009 10.1021/ol5005752 1523-7052 Enantioenriched Al-, Mg-, and Zn-enolates undergo electrophilic trapping by nitroolefins and vinylsulfones to afford 1,4-diketones and 2-(bis(phenylsulfonyl)ethyl)ketones in good yield and excellent diastereoselectivity. A one-pot preparation of indenes and enantiopure syntheses of tetrahydrobenzofurans, tetrahydrobenzopyrroles, and azulenes are disclosed. A site-selective two-step sequence of three conjugate additions is also demonstrated. Dewey 540 36 Département de chimie organique 141 false Organic letters 16 7 28a54c0d-0341-4f33-81ee-b1329770c179 Article (Published version) Restricted ol5005752.pdf 446910 application/pdf restrictedAccess Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Title	Published in	Access level	OA Policy	Year	Views	Downloads

Domino Asymmetric Conjugate Addition–Conjugate Addition	Organic letters			2014	722	7

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Schlaefli, Dorian