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Titles listSolvatochromic analysis of di-n-butyl ether/water partition coefficients as compared to other solvent systems
Titles listSolvatochromic analysis of di-n-butyl ether/water partition coefficients as compared to other solvent systems
Scientific Article
unige:9955 
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Solvatochromic analysis of di-n-butyl ether/water partition coefficients as compared to other solvent systems |
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| Authors | ||
| Published in | Journal of the Chemical Society. Perkin transactions II. 1997, no. 12, p. 2639-2643 | |
| Abstract | In order to assess the molecular parameters controlling partition coefficients in the di-n-butyl ether/water system, a set of 43 solutes has been selected. Centrifugal partition chromatography and the pi-I-metric method have been used to measure log P-dbe values. Using linear solvation Gibbs-energy relationship analyses, the balance of intermolecular forces governing the di-n-butyl ether partition coefficient has been identified, indicating that the partitioning of H-bond accepters is less important in the di-n-butyl ether/water system than in the n-octanol/water system. The di-n-butyl ether/water system appears to be a valuable substitute to propyleneglycol dipelargolate/water in the detailed characterisation of intermolecular interactions of complex compounds using the (critical quarter) methodology | |
| Identifiers | DOI: 10.1039/a704962e | |
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| Citation (ISO format) | PAGLIARA, Alessandra et al. Solvatochromic analysis of di-n-butyl ether/water partition coefficients as compared to other solvent systems. In: Journal of the Chemical Society. Perkin transactions II, 1997, n° 12, p. 2639-2643. doi: 10.1039/a704962e https://archive-ouverte.unige.ch/unige:9955 |
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