Copper-mediated asymmetric transformations

Alexakis, Alexandre

doi:10.1351/pac200274010037

Scientific article

English

Copper-mediated asymmetric transformations

ContributorsAlexakis, Alexandre

Published inPure and applied chemistry, vol. 74, no. 1, p. 37-42

Publication date2002

Abstract

Copper-catalyzed reactions include the enantioselective conjugate addition and the SN2¢ substitution. We describe the genesis of these reactions, the choice of the primary organometallic reagent, and our studies on finding new Michael acceptors and new ligands. We also report on the use of the zinc enolate generated upon conjugate addition.

Note11th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-11). - Taipei (Taiwan). - 22-26 july 2001

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

ALEXAKIS, Alexandre. Copper-mediated asymmetric transformations. In: Pure and applied chemistry, 2002, vol. 74, n° 1, p. 37–42. doi: 10.1351/pac200274010037

Article

Identifiers

PID : unige:9591
DOI : 10.1351/pac200274010037

Commercial URLhttp://iupac.org/publications/pac/74/1/0037/

Journal ISSN0033-4545

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Creation12/07/2010 14:37:44

First validation12/07/2010 14:37:44

Update time14/03/2023 15:55:03

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Copper-mediated asymmetric transformations

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