Scientific article
OA Policy
English

Critical scattering and incommensurate phase transition in antiferroelectric PbZrO3 under pressure

Published inScientific reports, vol. 7, 41512
Publication date2017
Abstract

Antiferroelectric lead zirconate is the key ingredient in modern ferroelectric and piezoelectric functional solid solutions. By itself it offers opportunities in new-type non-volatile memory and energy storage applications. A highly useful and scientifically puzzling feature of this material is the competition between the ferro- and antiferroelectric phases due to their energetic proximity, which leads to a challenge in understanding of the critical phenomena driving the formation of the antiferroelectric structure. We show that application of hydrostatic pressure drastically changes the character of critical lattice dynamics and enables the soft-mode-driven incommensurate phase transition sequence in lead zirconate. In addition to the long known cubic and antiferroelectric phases we identify the new non-modulated phase serving as a bridge between the cubic and the incommensurate phases. The pressure effect on ferroelectric and incommensurate critical dynamics shows that lead zirconate is not a single-instability-driven system.

Research groups
Citation (ISO format)
BURKOVSKY, R. G. et al. Critical scattering and incommensurate phase transition in antiferroelectric PbZrO3 under pressure. In: Scientific reports, 2017, vol. 7, p. 41512. doi: 10.1038/srep41512
Main files (1)
Article (Published version)
accessLevelPublic
Identifiers
Additional URL for this publicationhttp://www.nature.com/articles/srep41512
Journal ISSN2045-2322
499views
245downloads

Technical informations

Creation05/02/2017 18:28:00
First validation05/02/2017 18:28:00
Update time15/03/2023 01:21:16
Status update15/03/2023 01:21:15
Last indexation31/10/2024 06:05:31
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack