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Application of Electrospray Mass Spectrometry for Characterizing Supramolecular Coordination Complexes

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Hopfgartner, Gérard
Henion, Jack D.
Published in Helvetica Chimica Acta. 1993, vol. 76, no. 4, p. 1759-1766
Abstract The Electrospray Mass Spectrometry (ES-MS) of eight different supramolecular complexes shows that the molecular peaks of the desolvated multiply charged cations can be recorded more easily than by Fast-Atom-Bom-bardment Mass Spectrometry (FAB-MS) measurements of similar compound. The preliminary application of the ES-MS technique to self-assembled helical complexes obtained from ligands L3 to L8 with various metal ions (Cu, Co, Eu, Tb) indicates that ES mass spectra qualitatively reflect the species present MeCN solution.
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Other version: http://doi.wiley.com/10.1002/hlca.19930760432
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HOPFGARTNER, Gérard et al. Application of Electrospray Mass Spectrometry for Characterizing Supramolecular Coordination Complexes. In: Helvetica Chimica Acta, 1993, vol. 76, n° 4, p. 1759-1766. https://archive-ouverte.unige.ch/unige:84789

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Deposited on : 2016-06-28

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