Scientific article
English

Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents

Published in

Tetrahedron letters, vol. 50, no. 26, p. 3474-3477

Publication date

2009

Abstract

The desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand is described. The corresponding homoallylic alcohols are obtained in high yield, diastereoselectivity, and enantiomeric excess. Furthermore the first anti enantioselective desymmetrization with aromatic nucleophiles is reported.

Citation (ISO format)

MILLET, Renaud et al. Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents. In: Tetrahedron letters, 2009, vol. 50, n° 26, p. 3474–3477. doi: 10.1016/j.tetlet.2009.02.219

Main files (1)

Article (Published version)

Identifiers

Journal ISSN

0040-4039
576views
0downloads

Technical informations

Creation

25/06/2010 17:41:00

First validation

25/06/2010 17:41:00

Update

14/03/2023 15:49:29

Status update

14/03/2023 15:49:29

Last indexation

29/10/2024 15:41:43
All rights reserved by Archive ouverte UNIGE and the University of Geneva
OpenAIRE Indexed & Validated