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Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents

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Bernardez, Tania
Published in Tetrahedron Letters. 2009, vol. 50, no. 26, p. 3474 - 3477
Abstract The desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand is described. The corresponding homoallylic alcohols are obtained in high yield, diastereoselectivity, and enantiomeric excess. Furthermore the first anti enantioselective desymmetrization with aromatic nucleophiles is reported.
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MILLET, Renaud et al. Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents. In: Tetrahedron Letters, 2009, vol. 50, n° 26, p. 3474 - 3477. https://archive-ouverte.unige.ch/unige:8478

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Deposited on : 2010-06-28

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