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Copper-catalyzed asymmetric conjugate addition with Grignard reagents and SimplePhos ligands

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Published in Tetrahedron: Asymmetry. 2009, vol. 20, no. 24, p. 2866 - 2870
Abstract Herein we report the copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic and acyclic enones, with SimplePhos as chiral ligands. A variety of Grignard reagents can be added to a range of cyclic and acyclic enones, with moderate to good enantioselectivities (ee's up to 86%).
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PALAIS, Laetitia, ALEXAKIS, Alexandre. Copper-catalyzed asymmetric conjugate addition with Grignard reagents and SimplePhos ligands. In: Tetrahedron: Asymmetry, 2009, vol. 20, n° 24, p. 2866 - 2870. https://archive-ouverte.unige.ch/unige:8459

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Deposited on : 2010-06-25

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