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Title

Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical Reactivity

Authors
Gerecke, Mario
Grampp, Günter
Milkiewicz, Jadwiga
Radzewicz, Czesław
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Published in Physical Chemistry Chemical Physics. 2016, vol. 18, p. 18460-18469
Abstract The properties of binary mixtures of dimethylsulfoxide and glycerol, measured by several techniques, are reported. Special attention is given to those properties contributing or affecting chemical reactions. In this respect the investigated mixture behaves as a relatively simple solvent and it is especially well suited for studies on the influence of viscosity in chemical reactivity. This is due to the relative invariance of the dielectric properties of the mixture. However, special caution must be taken with specific solvation, as the hydrogen-bonding properties of the solvent changes with the molar fraction of glycerol.
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Note 49 pages including appendix, 20 figures and 89 references
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Research groups Groupe Vauthey
Groupe Adibekian
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ANGULO NUNEZ, Gonzalo Manuel et al. Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical Reactivity. In: Physical Chemistry Chemical Physics, 2016, vol. 18, p. 18460-18469. https://archive-ouverte.unige.ch/unige:83511

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Deposited on : 2016-05-03

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