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Scientific article
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Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of "Friction-Dependent" Chemical Reactivity

Published inPhysical Chemistry Chemical Physics, vol. 18, p. 18460-18469
Publication date2016
Abstract

The properties of binary mixtures of dimethylsulfoxide and glycerol, measured by several techniques, are reported. Special attention is given to those properties contributing or affecting chemical reactions. In this respect the investigated mixture behaves as a relatively simple solvent and it is especially well suited for studies on the influence of viscosity in chemical reactivity. This is due to the relative invariance of the dielectric properties of the mixture. However, special caution must be taken with specific solvation, as the hydrogen-bonding properties of the solvent changes with the molar fraction of glycerol.

Classification
  • arxiv : physics.chem-ph
Note49 pages including appendix, 20 figures and 89 references
Citation (ISO format)
ANGULO NUNEZ, Gonzalo Manuel et al. Characterization of Dimethylsulfoxide / Glycerol Mixtures: A Binary Solvent System for the Study of ‘Friction-Dependent’ Chemical Reactivity. In: Physical Chemistry Chemical Physics, 2016, vol. 18, p. 18460–18469. doi: 10.1039/C6CP02997C
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Creation04/22/2016 10:08:00 AM
First validation04/22/2016 10:08:00 AM
Update time03/15/2023 12:19:21 AM
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