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SimplePhos as efficient ligands for the copper-catalysed kinetic resolution of cyclic vinyloxiranes with grignard reaggents

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Published in Synlett. 2008, no. 12, p. 1797-1800
Abstract Cyclic vinyloxiranes react with Grignard reagents under copper catalysis. Highly efficient kinetic resolution is achieved with the new SimplePhos family of chiral phosphorus ligands. Stereodivergence could be exploited to get either the SN2 or SN2' product with up to 96% ee.
Keywords EpoxidesAsymmetric synthesisGrignard reagentsCatalysisCopper
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MILLET, Renaud, ALEXAKIS, Alexandre. SimplePhos as efficient ligands for the copper-catalysed kinetic resolution of cyclic vinyloxiranes with grignard reaggents. In: Synlett, 2008, n° 12, p. 1797-1800. https://archive-ouverte.unige.ch/unige:8237

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Deposited on : 2010-06-21

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