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Copper-catalysed asymmetric allylic alkylation

Published in European Journal of Organic Chemistry. 2008, no. 22, p. 3765-3780
Abstract Over the past decade, much effort has been put on designing efficient chiral ligands and screening of the different parameters that govern the main challenges of asymmetric SN2 reactions, namely chemo-, regio- and enantioselectivity. This review traces the evolution of the methodologies for creating stereogenic centers through asymmetric copper-catalyzed allylic alkylation with the use of different organometallic reagents and their subsequent applications.
Keywords CopperAllylic compoundsAsymmetric catalysis
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FALCIOLA, Caroline Alexandra, ALEXAKIS, Alexandre. Copper-catalysed asymmetric allylic alkylation. In: European Journal of Organic Chemistry, 2008, n° 22, p. 3765-3780. doi: 10.1002/ejoc.200800025 https://archive-ouverte.unige.ch/unige:8233

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Deposited on : 2010-06-21

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