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Scientific article
English

Organo-vinyl-copper compounds V. Regioselectivity in the addition of alkyl-copper-magnesium bromide reagents on various propargyl derivatives

Published inJournal of molecular catalysis. A, Chemical, vol. 1, no. 1, p. 43-58
Publication date1975
Abstract

The syn addition of alkylcopper reagents to various propargyl derivatives, i.e. HCtriple bond; length as m-dashC---C---Z (Z=X, OAc, NR2, SEt, OR, O-), has been studied. Among the various factors governing the regioselectivity, the nature of the heteroatom in the group Z and the polarity of the solvent are particularly important. The vinylcopper derivatives obtained from propargyl ethers have been carboxylated, iodinated and oxidised.

Affiliation Not a UNIGE publication
Citation (ISO format)
ALEXAKIS, Alexandre, NORMANT, Jean F., VILLIERAS, Jean. Organo-vinyl-copper compounds V. Regioselectivity in the addition of alkyl-copper-magnesium bromide reagents on various propargyl derivatives. In: Journal of molecular catalysis. A, Chemical, 1975, vol. 1, n° 1, p. 43–58. doi: 10.1016/0304-5102(75)80006-X
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ISSN of the journal1381-1169
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