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Title

Regioselective SN2 opening of α,β-ethylenic epoxides by RLi-BF3 combination

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Vrancken, Emmanuel
Mangeney, Pierre
Chemla, Fabrice
Published in Perkin Transactions 1. 2000, no. 20, p. 3352-3353
Abstract Organolithium reagents effect a regioselective SN2 nucleophilic cleavage of a,ß-ethylenic epoxides only when BF3·Et2O is added. The reaction works with a variety of RLi reagents and with cyclic as well as acyclic epoxides.
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ALEXAKIS, Alexandre et al. Regioselective SN2 opening of α,β-ethylenic epoxides by RLi-BF3 combination. In: Perkin Transactions 1, 2000, n° 20, p. 3352-3353. https://archive-ouverte.unige.ch/unige:8217

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Deposited on : 2010-06-21

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