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Scientific article
English

Regioselective SN2 opening of α,β-ethylenic epoxides by RLi-BF3 combination

Publication date2000
Abstract

Organolithium reagents effect a regioselective SN2 nucleophilic cleavage of a,ß-ethylenic epoxides only when BF3·Et2O is added. The reaction works with a variety of RLi reagents and with cyclic as well as acyclic epoxides.

Citation (ISO format)
ALEXAKIS, Alexandre et al. Regioselective SN2 opening of α,β-ethylenic epoxides by RLi-BF3 combination. In: Journal of the Chemical Society. Perkin transactions 1, 2000, n° 20, p. 3352–3353. doi: 10.1039/b005472k
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ISSN of the journal1364-5463
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First validation06/21/2010 2:44:42 PM
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