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Asymmetric cleavage of chiral acetals by R2CuLi,BF3 reagents

Ghribi, A.
Normant, Jean F.
Published in Tetrahedron Letters. 1984, vol. 25, no. 29, p. 3083-3086
Abstract The title reagents cleave diastereoselectively the acetals derived from various aldehydes and chiral 2–3 butane diol (or higher homologs). This reaction affords an asymetric synthesis of secondary alcohols from an aldehyde and a trivial organolithium reagent.
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GHRIBI, A., ALEXAKIS, Alexandre, NORMANT, Jean F. Asymmetric cleavage of chiral acetals by R2CuLi,BF3 reagents. In: Tetrahedron Letters, 1984, vol. 25, n° 29, p. 3083-3086. doi: 10.1016/0040-4039(84)80013-1

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Deposited on : 2010-06-21

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