en
Scientific article
Letter
English

Reactivity of RCu,BF3 and R2CuLi,BF3 toward the ether linkage. Epoxides, acetals and orthoformates

Published inTetrahedron letters, vol. 25, no. 29, p. 3075-3078
Publication date1984
Abstract

The association of BF3 to organocopper and cuprate reagents increases dramatically their reactivity towards epoxides. The same reagents cleave acetals to afford the product of substitution of one alkoxy group, whereas orthoformates lead to acetals under conditions where no further attack occurs.

Affiliation Not a UNIGE publication
Citation (ISO format)
GHRIBI, A., ALEXAKIS, Alexandre, NORMANT, Jean F. Reactivity of RCu,BF3 and R2CuLi,BF3 toward the ether linkage. Epoxides, acetals and orthoformates. In: Tetrahedron letters, 1984, vol. 25, n° 29, p. 3075–3078. doi: 10.1016/0040-4039(84)80011-8
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ISSN of the journal0040-4039
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