Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents

Germon, C.; Alexakis, Alexandre; Normant, Jean F.

doi:10.1016/0040-4039(80)80172-9

Article scientifique

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Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents

Contributeurs/tricesGermon, C.; Alexakis, Alexandre; Normant, Jean F.

Publié dansTetrahedron letters, vol. 21, no. 39, p. 3763-3766

Date de publication1980

Résumé

the carbocupration or hydroalumination of alkynes followed by amino-methylation yields allylic amines. The stereochemical integrity of the alkenyl moiety is completely retained in both cases.

Structure d'affiliation Pas une publication de l'UNIGE

Citation (format ISO)

GERMON, C., ALEXAKIS, Alexandre, NORMANT, Jean F. Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents. In: Tetrahedron letters, 1980, vol. 21, n° 39, p. 3763–3766. doi: 10.1016/0040-4039(80)80172-9

Article (Published version)

Identifiants

PID : unige:8196
DOI : 10.1016/0040-4039(80)80172-9

ISSN du journal0040-4039

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Heure de mise à jour14.03.2023 15:48:31

Changement de statut14.03.2023 15:48:31

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Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents

the carbocupration or hydroalumination of alkynes followed by amino-methylation yields allylic amines. The stereochemical integrity of the alkenyl moiety is completely retained in both cases.

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