Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents

Germon, C.; Alexakis, Alexandre; Normant, Jean F.

doi:10.1016/0040-4039(80)80172-9

Scientific article

Letter

English

Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents

ContributorsGermon, C.; Alexakis, Alexandre; Normant, Jean F.

Published inTetrahedron letters, vol. 21, no. 39, p. 3763-3766

Publication date1980

Abstract

the carbocupration or hydroalumination of alkynes followed by amino-methylation yields allylic amines. The stereochemical integrity of the alkenyl moiety is completely retained in both cases.

Affiliation entities

Not a UNIGE publication

Citation (ISO format)

GERMON, C., ALEXAKIS, Alexandre, NORMANT, Jean F. Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents. In: Tetrahedron letters, 1980, vol. 21, n° 39, p. 3763–3766. doi: 10.1016/0040-4039(80)80172-9

Article (Published version)

Identifiers

PID : unige:8196
DOI : 10.1016/0040-4039(80)80172-9

Journal ISSN0040-4039

577views

0downloads

Creation21/06/2010 14:44:34

First validation21/06/2010 14:44:34

Update14/03/2023 15:48:31

Status update14/03/2023 15:48:31

Last indexation29/10/2024 15:34:58

Archive ouverte UNIGE

Vinyl-copper derivatives. XII. Stereospecific synthesis of allylic amines by aminomethylation of organocopper reagents

the carbocupration or hydroalumination of alkynes followed by amino-methylation yields allylic amines. The stereochemical integrity of the alkenyl moiety is completely retained in both cases.

Technical informations