Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes

Commerçon, M.; Mangeney, Pierre; Tejero, T.; Alexakis, Alexandre

doi:10.1016/S0957-4166(00)86315-6

Scientific article

English

Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes

ContributorsCommerçon, M.; Mangeney, Pierre; Tejero, T.; Alexakis, Alexandre

Published inTetrahedron: asymmetry, vol. 1, no. 5, p. 287-289

Publication date1990

Abstract

Chiral aryl metallic derivatives are generated from chiral o-bromo imidazolidines or acetals, prepared from chiral diols or diamines having a C2 axis of symmetry. These reagents react with aldehydes with moderate to high diastereoselectivities. Removal of the chiral auxiliary, then leads to homochiral lactols 7.

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Citation (ISO format)

COMMERÇON, M. et al. Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes. In: Tetrahedron: asymmetry, 1990, vol. 1, n° 5, p. 287–289. doi: 10.1016/S0957-4166(00)86315-6

Article (Published version)

Identifiers

PID : unige:8179
DOI : 10.1016/S0957-4166(00)86315-6

Journal ISSN0957-4166

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Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes

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