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Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes |
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Published in | Tetrahedron: Asymmetry. 1990, vol. 1, no. 5, p. 287-289 | |
Abstract | Chiral aryl metallic derivatives are generated from chiral o-bromo imidazolidines or acetals, prepared from chiral diols or diamines having a C2 axis of symmetry. These reagents react with aldehydes with moderate to high diastereoselectivities. Removal of the chiral auxiliary, then leads to homochiral lactols 7. | |
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Citation (ISO format) | COMMERÇON, M. et al. Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes. In: Tetrahedron: Asymmetry, 1990, vol. 1, n° 5, p. 287-289. doi: 10.1016/S0957-4166(00)86315-6 https://archive-ouverte.unige.ch/unige:8179 |