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Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes

Authors
Commerçon, M.
Mangeney, Pierre
Tejero, T.
Published in Tetrahedron: Asymmetry. 1990, vol. 1, no. 5, p. 287-289
Abstract Chiral aryl metallic derivatives are generated from chiral o-bromo imidazolidines or acetals, prepared from chiral diols or diamines having a C2 axis of symmetry. These reagents react with aldehydes with moderate to high diastereoselectivities. Removal of the chiral auxiliary, then leads to homochiral lactols 7.
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COMMERÇON, M. et al. Chiral aminal templates 4. Chiral aryl metallic reagents: reactions with aldehydes. In: Tetrahedron: Asymmetry, 1990, vol. 1, n° 5, p. 287-289. https://archive-ouverte.unige.ch/unige:8179

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Deposited on : 2010-06-21

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