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Title

Boron trifluoride assisted opening of epoxides by lithium alkenyl aluminate reagents

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Jachiet, D.
Published in Tetrahedron. 1989, vol. 45, no. 19, p. 6197-6202
Abstract Alkenyl aluminate reagents, obtained by hydroalumination of terminal alkynes followed by Image complexation with Meli, react readily with poorly reactive cyclic ethers such as cyclohexene oxide and oxetane, in the presence of BF3·Et2O. Alkenyl aluminate reagents obtained by reaction of an alkenyl tithium reagent and Me3Al behave similarly.
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ALEXAKIS, Alexandre, JACHIET, D. Boron trifluoride assisted opening of epoxides by lithium alkenyl aluminate reagents. In: Tetrahedron, 1989, vol. 45, n° 19, p. 6197-6202. https://archive-ouverte.unige.ch/unige:8171

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Deposited on : 2010-06-21

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