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Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex

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Rose-Munch, Françoise
Gagliardini, Vanessa
Perrotey, Anne
Tranchier, Jean-Philippe
Rose, Eric
Mangeney, Pierre
Kanger, Tonis
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Published in Chemical Communications. 1999, vol. 34, no. 20, p. 2061-2062
Abstract Tricarbonylphthalaldehydechromium complex can be prepared using a one pot procedure starting from tricarbonylbenzenechromium: the protection of one aldehyde function by chiral diamines leads to the formation of two diastereoisomers of the monoaminal of the phthlaldehyde complexes, efficient precursors of enantiopure ortho-substituted alkenyl arene complexes.
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ROSE-MUNCH, Françoise et al. Two-step synthesis of homochiral monoaminals of tricarbonylphthalaldehydechromium complex. In: Chemical Communications, 1999, vol. 34, n° 20, p. 2061-2062. https://archive-ouverte.unige.ch/unige:8162

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Deposited on : 2010-06-21

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