Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR

Chauvin, Anne-Sophie; Alexakis, Alexandre

doi:10.1186/1860-5397-2-6

Scientific article

Open access

English

Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR

ContributorsChauvin, Anne-Sophie; Alexakis, Alexandre

Published inBeilstein journal of organic chemistry, vol. 2, no. 6

Publication date2006

Abstract

The use of organophosphorus derivatising agents, prepared from C2 symmetric trimethylsilylated diamines, for the 1H NMR and 31P NMR determination of the enantiomeric composition of chiral alcohols is described.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

CHAUVIN, Anne-Sophie, ALEXAKIS, Alexandre. Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR. In: Beilstein journal of organic chemistry, 2006, vol. 2, n° 6. doi: 10.1186/1860-5397-2-6

Article (Published version)

CC BY

Identifiers

PID : unige:8124
DOI : 10.1186/1860-5397-2-6
PMID : 16566844

ISSN of the journal1860-5397

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Chiral trimethylsilylated C2-symmetrical diamines as phosphorous derivatizing agents for the determination of the enantiomeric excess of chiral alcohols by 1H NMR

The use of organophosphorus derivatising agents, prepared from C2 symmetric trimethylsilylated diamines, for the 1H NMR and 31P NMR determination of the enantiomeric composition of chiral alcohols is described.

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