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Structure ofRNi3Al9(R= Y, Gd, Dy, Er) with either ordered or partly disordered arrangement of Al-atom triangles and rare-earth-metal atoms

Published inActa crystallographica. Section B, Structural science, vol. 49, no. 3, p. 468-474
Publication date1993
Abstract

ErNi3A19, Mr = 586.22, trigonal, new type, hR78, R32 - f2edc4 (No. 155), a = 7.2716 (5), c=27.346 (3) A, V = 1252.2 (2)A3, Z = 6, Dx = 4.664 Mg m -3, A(Mo Ka) = 0.71073/k, u = 17.654 mm-1, F(000) = 1614, T = 293 K, wR = 0.021 for 785 contributing unique reflections. The structure is built up of three kinds of monoatomic layer perpendicular to c: Al-atom layers with triangular mesh, Ni-atom layers with triangular mesh and layers containing two rare-earth-metal atoms for one Al-atom triangle. GdNi3A19 [a = 7.3006 (9), c = 27.478 (5)/A, wR = 0.020 for 791 reflections] is isotypic. YNi3AI9 [a = 7.2894 (7), c = 27.430 (5) A, wR =0.035 for 635 reflections] and DyNi3AI9 [a = 7.2723 (9), c = 27.344 (6)A, wR = 0.027 for 682 reflections] crystallize in related structures with a partly disordered arrangement of Al-atom triangles and rare-earth-metal atoms. Similar monoatomic layers to those in ErNi3AI9 build up the orthorhombic structure of Y2Co3AI9 (Y2Co3Ga9 type). The stoichiometry 1:3:9 is related to that of RzT3A19 by replacing every second mixed layer of composition R2AI3 by an Al-atom layer (A13): 6RT3A19 = 6R2T3AI9 - 3R2AI3 + 3A13.

Citation (ISO format)
GLADYSHEVSKII, Roman et al. Structure ofRNi3Al9(R= Y, Gd, Dy, Er) with either ordered or partly disordered arrangement of Al-atom triangles and rare-earth-metal atoms. In: Acta crystallographica. Section B, Structural science, 1993, vol. 49, n° 3, p. 468–474. doi: 10.1107/S010876819201173X
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