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Title

(2RS)-4,4-Dimethyl-2-[(1SR)-1-phenylethyl]-1-pyrrolidinol

Authors
Oppolzer, Wolfgang
Published in Acta Crystallographica. C, Crystal Structure Communications. 1995, vol. 51, no. 3, p. 529-530
Abstract In order to determine the stereospecificity of the Thermal cyclization of [(E)-2,2-dimethyl-5-phenyl-4- hexenyl] hydroxylamine (1), the relative configuration of the title compound, C<sub>14</sub>H<sub>21</sub> NO, (2), has been established by single-crystal X-ray diffraction. The pyrrolidine ring adopts an envelope conformation with the N atom out of the ring plane. The molecules form hydrogen-bonded pairs through a centre of inversion [O...N 2.808 (5) A, and O---H...N 160 (4) °].
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BERNARDINELLI, Gérald Hugues, OPPOLZER, Wolfgang, SPIVEY, Alan Christopher. (2RS)-4,4-Dimethyl-2-[(1SR)-1-phenylethyl]-1-pyrrolidinol. In: Acta Crystallographica. C, Crystal Structure Communications, 1995, vol. 51, n° 3, p. 529-530. https://archive-ouverte.unige.ch/unige:81160

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