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Determination of the absolute configuration of chiral cyclic alcohols using diamine derivatizing agents by 31P NMR spectroscopy

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Published in Tetrahedron: Asymmetry. 2006, vol. 17, no. 15, p. 2203-2209
Abstract The absolute configuration and enantiomeric excess of chiral cyclic alcohols can be predicted from the 31P NMR spectra of the two diastereoisomers obtained with organophosphorus diamino-derivatizing agents (CDAs) and the chiral secondary alcohol, according to a simplified model taking into account the spatial location of the substituents of the chiral alcohol center and the 31P NMR signals of the two diastereoisomers.
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CHAUVIN, Anne-Sophie, BERNARDINELLI, Gérald Hugues, ALEXAKIS, Alexandre. Determination of the absolute configuration of chiral cyclic alcohols using diamine derivatizing agents by 31P NMR spectroscopy. In: Tetrahedron: Asymmetry, 2006, vol. 17, n° 15, p. 2203-2209. https://archive-ouverte.unige.ch/unige:8116

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Deposited on : 2010-06-21

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