A new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines

Gille, Segolene; Cabello, Noemi; Kizirian, Jean-Claude; Alexakis, Alexandre

doi:10.1016/j.tetasy.2006.03.026

Scientific article

English

A new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines

ContributorsGille, Segolene; Cabello, Noemi; Kizirian, Jean-Claude; Alexakis, Alexandre

Published inTetrahedron: asymmetry, vol. 17, no. 7, p. 1045-1047

Publication date2006

Abstract

New tertiary pseudo C2-symmetric 1,2-diamine 2b was synthesized and compared to 1b in the enantioselective addition of MeLi to imines 3a–f. Comparable selectivity and better reactivity were observed with this novel diamine.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

GILLE, Segolene et al. A new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines. In: Tetrahedron: asymmetry, 2006, vol. 17, n° 7, p. 1045–1047. doi: 10.1016/j.tetasy.2006.03.026

Article (Published version)

Identifiers

PID : unige:8107
DOI : 10.1016/j.tetasy.2006.03.026

ISSN of the journal0957-4166

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A new pseudo C2-symmetric tertiary diamine for the enantioselective addition of MeLi to aromatic imines

New tertiary pseudo C2-symmetric 1,2-diamine 2b was synthesized and compared to 1b in the enantioselective addition of MeLi to imines 3a–f. Comparable selectivity and better reactivity were observed with this novel diamine.

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