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Diversity-oriented synthesis towards conceptually new highly modular organocatalysts

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Published in Chemistry - A European Journal. 2008, vol. 14, no. 25, p. 7504-7507
Abstract A conceptually new family of modular aminal-pyrrolidine organocatalysts was prepared by diversity-oriented synthesis. The catalytic properties of these organocatalysts could easily be tuned by varying the different substituents on the aminal part. Good yields and enantioselectivities up to 91 % were obtained in Michael additions to nitroolefins or vinyl sulfones.
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PMID: 18666273
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QUINTARD, Adrien, BOURNAUD, Chloee Julie, ALEXAKIS, Alexandre. Diversity-oriented synthesis towards conceptually new highly modular organocatalysts. In: Chemistry - A European Journal, 2008, vol. 14, n° 25, p. 7504-7507. https://archive-ouverte.unige.ch/unige:8104

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Deposited on : 2010-06-21

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