The copper-catalyzed asymmetric allylic alkylation has shown through many examples that it is a powerful means to generate stereogenic centers with mono - and -substituted olefinic substrates. However, little has been reported about more substituted olefinic patterns, such as -disubstituted allylic electrophiles. In this paper, we show that a simple procedure using easily accessible Grignard reagents and as low as 3 mol% of copper/ligand can promote high to nearly perfect enantioselectivities (up to >99% ee) with very good -selectivities on a wide panel of aliphatic or aromatic -disubstituted substrates.