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Enantioselective addition of aryllithium reagents to aromatic imines mediated by 1,2-diamine ligands

Authors
Cabello, Noemi
Published in Tetrahedron Letters. 2004, vol. 45, no. 24, p. 4639-4642
Abstract A variety of optically enriched amines have been obtained by addition of aryllithium reagents to aromatic imines using N,N'-tetramethylcyclohexane-1,2-diamine as chiral ligands. Enantiomeric excesses up to 90% could be obtained.
Keywords DiarylmethylaminesOrganolithiumAsymmetryDiaminesChiral ligandsAddition to imines
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CABELLO, Noemi, KIZIRIAN, Jean-Claude, ALEXAKIS, Alexandre. Enantioselective addition of aryllithium reagents to aromatic imines mediated by 1,2-diamine ligands. In: Tetrahedron Letters, 2004, vol. 45, n° 24, p. 4639-4642. https://archive-ouverte.unige.ch/unige:8096

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Deposited on : 2010-06-21

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