en
Scientific article
Letter
English

Enantioselective addition of aryllithium reagents to aromatic imines mediated by 1,2-diamine ligands

Published inTetrahedron letters, vol. 45, no. 24, p. 4639-4642
Publication date2004
Abstract

A variety of optically enriched amines have been obtained by addition of aryllithium reagents to aromatic imines using N,N'-tetramethylcyclohexane-1,2-diamine as chiral ligands. Enantiomeric excesses up to 90% could be obtained.

Keywords
  • Diarylmethylamines
  • Organolithium
  • Asymmetry
  • Diamines
  • Chiral ligands
  • Addition to imines
Citation (ISO format)
CABELLO, Noemi, KIZIRIAN, Jean-Claude, ALEXAKIS, Alexandre. Enantioselective addition of aryllithium reagents to aromatic imines mediated by 1,2-diamine ligands. In: Tetrahedron letters, 2004, vol. 45, n° 24, p. 4639–4642. doi: 10.1016/j.tetlet.2004.04.100
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Article (Published version)
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Identifiers
ISSN of the journal0040-4039
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