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Title

Asymmetric synthesis of 1,2- and 1,4-dihydroquinolines

Authors
Rezgui, Farhat
Mangeney, Pierre
Published in Tetrahedron Letters. 1999, vol. 40, no. 34, p. 6241-6244
Abstract Asymmetric synthesis of dihydroquinolines by addition of organometallic reagents on a chiral 3-quinolinyl aminal was studied. 1,2-Adducts were obtained with good regio- and diastereoselectivity. The absolute configuration for 1,2-adducts was determined by X-ray analysis and for 1,4-adducts by chemical correlation. Asymmetric synthesis of dihydroquinolines by addition of organometallic reagents (RM) on a chiral 3-quinolinyl aminal was studied. 1,2-adducts were obtained with good regio- and diastereoselectivity.
Keywords Chiral diaminesAminalsDihydroquinolines
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REZGUI, Farhat, MANGENEY, Pierre, ALEXAKIS, Alexandre. Asymmetric synthesis of 1,2- and 1,4-dihydroquinolines. In: Tetrahedron Letters, 1999, vol. 40, n° 34, p. 6241-6244. https://archive-ouverte.unige.ch/unige:8092

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Deposited on : 2010-06-21

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