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Title

First diastereoselective asymmetric carbometallation of chiral vinyl metals

Authors
Brasseur, Denis
Rezaei, Hadi
Fuxa, Alain
Mangeney, Pierre
Marek, Ilan
Normant, Jean F.
Published in Tetrahedron Letters. 1998, vol. 39, no. 27, p. 4821-4824
Abstract Addition of substituted allylzinc reagents to chiral (Z) metallated allyl amines (or aminal) bearing a chiral aromatic moiety is face selective, and delivers ß-methylated amines with good diastereomeric excess.
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BRASSEUR, Denis et al. First diastereoselective asymmetric carbometallation of chiral vinyl metals. In: Tetrahedron Letters, 1998, vol. 39, n° 27, p. 4821-4824. https://archive-ouverte.unige.ch/unige:8090

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Deposited on : 2010-06-21

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