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Stereochemical effects of trimethylsilyl chloride (TMSCl) on the conjugate addition of organocopper reagents

Authors
Sedrani, R.
Mangeney, Pierre
Published in Tetrahedron Letters. 1990, vol. 31, no. 3, p. 345-348
Abstract The stereochemical course of the conjugate addition of organocopper reagents, in the presence of TMSCl, is not affected by remote chelation effects, whereas in its absence, the latter may predominate. By this way, it is possible to distinguish, the relative effects of the chelation and of the steric hindrance.
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ALEXAKIS, Alexandre, SEDRANI, R., MANGENEY, Pierre. Stereochemical effects of trimethylsilyl chloride (TMSCl) on the conjugate addition of organocopper reagents. In: Tetrahedron Letters, 1990, vol. 31, n° 3, p. 345-348. https://archive-ouverte.unige.ch/unige:8078

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