Scientific Article - Letter
previous document  unige:8075  next document
add to browser collection
Title

Diastereoselective synthesis of α-allenic alcohols from propargylic epoxides

Authors
Marek, Ilane
Mangeney, Pierre
Normant, Jean F.
Published in Tetrahedron Letters. 1989, vol. 30, no. 18, p. 2387-2390
Abstract The cuprocatalyzed reaction of a Grignard reagent with propargylic epoxides proceed through an addition-elimination mechanism. By changing the reaction conditions, particularly the halogen atom of RMgX it is possible to control the diastereoselectivity of the reaction. Both diastereoisomers of anf allenic alcohol can thus be obtained at will.
Identifiers
Full text
Article (Published version) - document accessible for UNIGE members only Limited access to UNIGE
Citation
(ISO format)
ALEXAKIS, Alexandre et al. Diastereoselective synthesis of α-allenic alcohols from propargylic epoxides. In: Tetrahedron Letters, 1989, vol. 30, n° 18, p. 2387-2390. https://archive-ouverte.unige.ch/unige:8075

119 hits

25 downloads

Update

Deposited on : 2010-06-21

Export document
Format :
Citation style :